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Spectroscopic and Computational Interrogation of a High-Valent Nickel-Dialkyl Complex Indicates Electronic Structure Asymmetry Drives C–C Bond Formation Reactivity 收藏

高价值镍二烷基络合物的光谱和计算询问表明电子结构不对称驱动C – C键的形成反应性
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摘要译文
Alina Yerbulekova; Yusuff Moshood; Leonel Griego; Hannah S. Shafaat*; and Liviu M. Mirica*. Spectroscopic and Computational Interrogation of a High-Valent Nickel-Dialkyl Complex Indicates Electronic Structure Asymmetry Drives C–C Bond Formation Reactivity[J]. Journal of the American Chemical Society, 2025,147(9): 7317-7324